Advances in Inorganic Chemistry: Inorganic Reaction by Colin D. Hubbard Rudi Van Eldik

By Colin D. Hubbard Rudi Van Eldik

The Advances in Inorganic Chemistry sequence provides well timed and informative summaries of the present growth in quite a few topic components inside of inorganic chemistry starting from bio-inorganic to strong kingdom experiences. This acclaimed serial beneficial properties studies written by means of specialists within the quarter and is an vital connection with complicated researchers. each one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is absolutely referenced. This, the 54th quantity within the sequence keeps this custom offering complete studies through best specialists within the box with the point of interest on inorganic and bioinorganic response mechanisms. * the most recent quantity during this hugely winning sequence is devoted to inorganic and bioinorganic response mechanisms* accomplished studies written by way of prime specialists within the box

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8 Id Id Id D and Id D D Ref. (254) (254) (255) (254) (254) (254) Six-coordinate ionic radii from Ref. (255). First-order rate constant for the exchange of a particular coordinated solvent molecule (6). 7 ^ ^ ^ D, Id D, Id D, Id D, Id D, Id D, Id Adapted from Refs. (56,257^259 ). a Six-coordinate ionic radii from Ref. (255). b First-order rate constant for the exchange of a particular coordinated solvent molecule (6). 2 for europium(II) (228). The water exchange rate measured on the divalent europium aqua ion is the fastest ever measured by 17O NMR (Table XVI) (2).

12). The water molecule coordination site is far less crowded and less electrostatically constrained in the ODDA2À than, for example, in the DOTA4À or DTPA5À complexes. 62 — for DTPA), and because of the much more open coordination site on [Eu(ODDA)(H2O)] allowing a second water molecule to approach the inner sphere. C. ACTINIDES Reports on studies of solvent exchange reactions on actinide compounds are very scarce. The most studied cation is UO2þ 2 . A. DUNAND et al. FIG. 12. X-ray structures of [Eu(DTPA)H2O]3À (left) and [Sr(ODDA)] (right).

Interchange rate constants, 3+ are shown as s, and water exchange ki, for the substitution of SO2À 4 on [Ln(H2O)n] rate constants, (298 K) for [Ln(H2O)8]3+ are shown as . Activation volumes, ÁV z, are shown as j. The picture for water exchange on the lanthanide ions, conceived on the basis of structural and kinetic results, is as follows (Fig. 10). Over the whole Ln3+ series eight- and nine-coordinate ions are close in energy. Nine coordination is favored for the larger ions and eight coordination for the smaller ones.

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